32nd vs thirty-second

32nd is not a noun while thirty-second is a noun.

Word	Noun	Adjective	Verb	Adverb
32nd	No	Yes	No	No
thirty-second	Yes	Yes	No	No

As adjectives, 32nd and thirty-second are synonyms defined as:

32nd and thirty-second: the ordinal number of thirty-two in counting order

32nd (noun)	thirty-second (noun)
	one part in thirty-two equal parts

32nd (adjective)	thirty-second (adjective)
the ordinal number of thirty-two in counting order	the ordinal number of thirty-two in counting order