Army National Guard vs military

Army National Guard and military both are nouns.

Word	Noun	Adjective	Verb	Adverb
Army National Guard	Yes	No	No	No
military	Yes	Yes	No	No

Army National Guard (noun)	military (noun)
a civilian reserve component of the United States Army comprised of guardsmen who serve during overseas peacekeeping missions and during local emergencies	the military forces of a nation

Army National Guard (adjective)	military (adjective)
	associated with or performed by members of the armed services as contrasted with civilians
	characteristic of or associated with soldiers or the military
	of or relating to the study of the principles of warfare