Great Britain vs all-mains

Great Britain is a noun but all-mains is not a noun.

Word	Noun	Adjective	Verb	Adverb
Great Britain	Yes	No	No	No
all-mains	No	Yes	No	No

Great Britain (noun)	all-mains (noun)
an island comprising England and Scotland and Wales
a monarchy in northwestern Europe occupying most of the British Isles; divided into England and Scotland and Wales and Northern Ireland; `Great Britain' is often used loosely to refer to the United Kingdom

Great Britain (adjective)	all-mains (adjective)
	used of a radio receiver that is adaptable to all voltages