devil vs rile

devil is a noun but rile is not a noun.

Word	Noun	Adjective	Verb	Adverb
devil	Yes	No	Yes	No
rile	No	No	Yes	No

As verbs, devil and rile are synonyms defined as:

devil and rile: cause annoyance in; disturb, especially by minor irritations

Other synonyms of devil include annoy, bother, chafe, get at, get to, gravel, irritate, nark, nettle, rag, vex.

devil (noun)	rile (noun)
a word used in exclamations of confusion
an evil supernatural being
a cruel wicked and inhuman person
a rowdy or mischievous person (usually a young man)

devil (verb)	rile (verb)
coat or stuff with a spicy paste	make turbid by stirring up the sediments of
cause annoyance in; disturb, especially by minor irritations	cause annoyance in; disturb, especially by minor irritations