extemporary vs ad-lib

extemporary is not a noun while ad-lib is a noun.

Word	Noun	Adjective	Verb	Adverb
extemporary	No	Yes	No	No
ad-lib	Yes	Yes	Yes	No

As adjectives, extemporary and ad-lib are synonyms defined as:

Other synonyms of extemporary include extemporaneous, extempore, impromptu, off-the-cuff, offhand, offhanded, unrehearsed.

extemporary (noun)	ad-lib (noun)
	remark made spontaneously without prior preparation

extemporary (adjective)	ad-lib (adjective)
with little or no preparation or forethought	with little or no preparation or forethought
	said or done without having been planned or written in advance

extemporary (verb)	ad-lib (verb)
	perform without preparation