garment vs enclothe

garment is a noun but enclothe is not a noun.

Word	Noun	Adjective	Verb	Adverb
garment	Yes	No	Yes	No
enclothe	No	No	Yes	No

As verbs, garment and enclothe are synonyms defined as:

Other synonyms of garment include apparel, clothe, dress, fit out, garb, habilitate, raiment, tog.

garment (noun)	enclothe (noun)
an article of clothing

garment (verb)	enclothe (verb)
provide with clothes or put clothes on	provide with clothes or put clothes on