peeve vs rile

peeve is a noun but rile is not a noun.

Word	Noun	Adjective	Verb	Adverb
peeve	Yes	No	Yes	No
rile	No	No	Yes	No

As verbs, rile is a hypernym of peeve; that is, rile is a word with a broader meaning than peeve:

Other hypernyms of peeve include annoy, bother, chafe, devil, get at, get to, gravel, irritate, nark, nettle, rag, vex.

peeve (noun)	rile (noun)
an annoyed or irritated mood

peeve (verb)	rile (verb)
cause to be annoyed, irritated, or resentful	make turbid by stirring up the sediments of
	cause annoyance in; disturb, especially by minor irritations