photographic print vs photo

photographic print and photo both are nouns.

Word	Noun	Adjective	Verb	Adverb
photographic print	Yes	No	No	No
photo	Yes	No	No	No

As nouns, photo is a hypernym of photographic print; that is, photo is a word with a broader meaning than photographic print:

photographic print: a printed picture produced from a photographic negative
photo: a representation of a person or scene in the form of a print or transparent slide or in digital format

Other hypernyms of photographic print include exposure, photograph, pic, picture.

photographic print (noun)	photo (noun)
a printed picture produced from a photographic negative	a representation of a person or scene in the form of a print or transparent slide or in digital format