toe vs pes

toe and pes both are nouns.

Word	Noun	Adjective	Verb	Adverb
toe	Yes	No	Yes	No
pes	Yes	No	No	No

toe (noun)	pes (noun)
the part of footwear that provides a covering for the toes	the part of the leg of a human being below the ankle joint
(golf) the part of a clubhead farthest from the shaft
one of the digits of the foot
forepart of a hoof

toe (verb)	pes (verb)
touch with the toe
hit (a golf ball) with the toe of the club
drive obliquely
drive (a golf ball) with the toe of the club
walk so that the toes assume an indicated position or direction