venturesome vs daring

venturesome is not a noun while daring is a noun.

Word	Noun	Adjective	Verb	Adverb
venturesome	No	Yes	No	No
daring	Yes	Yes	No	No

As adjectives, venturesome and daring are synonyms defined as:

Other synonyms of venturesome include audacious, venturous.

venturesome (noun)	daring (noun)
	the trait of being willing to undertake things that involve risk or danger
	a challenge to do something dangerous or foolhardy

venturesome (adjective)	daring (adjective)
disposed to venture or take risks	disposed to venture or take risks
	radically new or original