lollipop woman vs Great Britain

lollipop woman and Great Britain both are nouns.

Word	Noun	Adjective	Verb	Adverb
lollipop woman	Yes	No	No	No
Great Britain	Yes	No	No	No

lollipop woman (noun)	Great Britain (noun)
a woman hired to help children cross a road safely near a school	an island comprising England and Scotland and Wales
	a monarchy in northwestern Europe occupying most of the British Isles; divided into England and Scotland and Wales and Northern Ireland; `Great Britain' is often used loosely to refer to the United Kingdom